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Acetonitrile

Acetonitrile
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Product name: Acetonitrile CAS: 75-05-8 MF: C2H3N MW: 41.05

Product name: AcetonitrileCAS: 75-05-8 MF: C2H3N MW: 41.05

mp −48 °C(lit.)
bp 81-82 °C(lit.)
density 0.982 g/mL at 20 °C
vapor density 1.41 (vs air)
vapor pressure 72.8 mm Hg ( 20 °C)
refractive index n20/D 1.344(lit.)
Fp 48 °F
storage temp. 2-8°C
form liquid
color <10(APHA)
Water Solubility miscible

Acetonitrile Usage And Synthesis
Chemical PropertiesColorless liquid
General DescriptionA colorless limpid liquid with an aromatic odor. Flash point 42°F. Density 0.783 c / cm3. Toxic by skin absorption. Less dense than water. Vapors are denser than air.
Air & Water ReactionsHighly flammable. Water soluble.
Reactivity ProfileAcetonitrile decomposes when heated to produce deadly toxic hydrogen cyanide gas and oxides of nitrogen. Strongly reactive [Hawley]. May react vigorously with strong oxidizing reagents, sulfuric acid, chlorosulfonic acid, sulfur trioxide, perchlorates, nitrating reagents, and nitric acid. [Sax, 9th ed., 1996, p. 20]. Potentially explosive in contact with nitrogen-fluorine compounds (e.g., tetrafluorourea) [Fraser, G. W. et al., Chem. Comm., 1966, p. 532].
Health HazardExposure to 160 ppm for 4 hours causes flushing of the face and a feeling of constriction in the chest; 500 ppm for brief periods is irritating to the nose and throat. Severe exposures cause irritability, skin eruptions, confusion, delirium, convulsions, paralysis, and death due to central nervous system depression.

Acetonitrile



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